Determination of Q1, an unknown organochlorine contaminant, in human milk, Antarctic air, and further environmental samples

Q1, an organochlorine component with the molecular formula C(9)H(3)Cl(7)N(2) and of unknown origin was recently identified in seal blubber samples from the Namibian coast (southwest of Africa) and the Antarctic. In these samples, Q1 was more abundant than PCBs and on the level of DDT residues. Furthermore, Q1 was more abundant in seals from the Antarctic than the Arctic. To prove this assumption, gas chromatography-electron-capture negative ion mass spectrometry (GC/ECNI-MS), which is sensitive and selective for Q1, allowed for screening of traces of Q1 even in samples with particularly high levels of other organochlorine contaminants. Q1 was isolated by high-performance liquid chromatography (HPLC) from a skua liver sample. A 1:1 mixture with trans-nonachlor in electron-capture detectors (ECDs) was used to determine the relative response factor with ECNI-MS. The ECNI-MS response of Q1 turned out to be 4.5 times higher than that of trans-nonachlor in an ECD. With GC/ECNI-MS in the selected ion-monitoring mode, four Antarctic and four Arctic air samples were investigated for the presence of Q1. In the Antarctic air samples, Q1 levels ranged from 0.7 to 0.9 fg/m(3). In Arctic air samples, however, Q1 was below the detection limit (<0.06 fg/m(3) or 60 ag/m(3)). We also report on high Q1 levels in selected human milk samples (12-230 microg/kg lipid) and, therefore, suggested that the unknown Q1 is an environmental compound whose origin and distribution should be investigated in detail. Our data confirm that Q1 is a bioaccumulative natural organochlorine product. Detection of a highly chlorinated natural organochlorine compound in air and human milk is novel.     

Charity hazard—A real hazard to natural disaster insurance?

After the flooding in 2002 European governments provided billions of Euros of financial assistance to their citizens. Although there is no doubt that solidarity and some sort of assistance are reasonable, the question arises why these damages were not sufficiently insured. One explanation why individuals reject to obtain insurance cover against natural hazards is that they anticipate governmental and private aid. This problem became to be known as “charity hazard”. The present paper gives an economic analysis of the institutional arrangements on the market for natural disaster insurances focusing on imperfections caused by governmental financial relief. It provides a theoretical explanation why charity hazard is a problem on the market for natural disaster insurances, in the way that it acts as an obstacle for the proper diffusion and therefore the establishment of natural hazard insurances. This paper provides a review of the scientific discussion on charity hazard, provides a theoretical analysis and points out the existing empirical problems regarding this issue.     

Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review

Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However, the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties. In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed. Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates, permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites is reduced and their mechanical properties are improved.     

雾灵山自然保护区的生态效应与保护对策

通过对雾灵山国家级自然保护区的调查，研究保护区的生态沿革，分析保护区的生态功能、生态作用等生态效应，针对当前所存在的草甸严重退化、动物种群密度降低、水量减少等生态问题，提出对保护区的生态环境应尽快制定环境保护规范化，建立生物多样性保护权威机构，实行社区共管，开展科学生态旅游等措施。     

Natural control mechanisms in models of aquatic ecosystems

Based on cybernetic categories of natural control mechanisms, four generations of ecosystem models are distinguished: feed-forward, feedback, self-adaptation and self-organization models. The analysis of the natural control mechanisms in aquatic ecosystems suggests that different processes are controlled in different ways, and, although the four mechanisms were identified in historical sequence, they all operate simultaneously. The concept of self-organization of an ecosystem is introduced and specified for a model of an aquatic pelagic ecosystem. The concept of the ecosystem as a multilayer, multigoal and multiechelon hierarchical system with hierarchy of the levels of biological organization is also introduced.     

Application of a “closed-can” technique for measuring radon exhalation from mine samples of Punjab, Pakistan

Using the closed-can technique, radon exhalation rate measurements have been carried out for shale and coal samples collected from various mines located in the Chakwal and Makarwal areas of Pakistan. For the two areas, the measured average values of the exhalation rates from shale are 1.45±0.13 and 0.67±0.25 Bq m⁻² h⁻¹ and for coal are 1.0±0.03 and 0.65±0.32 Bq m⁻² h⁻¹, respectively. These values are much lower than the measured exhalation rates from alum-shale-based Nordic concrete which has values in the 50–200 Bq m⁻² h⁻¹ range. The lower values of the measured exhalation rates from the shale and coal deposits in the Chakwal and Makarwal areas are indicative of their lower uranium contents and mine workers in these areas do not face any abnormal health hazard due to radon since the exhalation rates have been found to be on the low side.     

Advancing urban ecosystem governance in New York City: Shifting towards a unified perspective for conservation management

New York City’s extensive municipal park system is home to forests, wetlands, and grasslands that provide important ecological and social benefits to the city’s population. While efforts and programs exist to restore and protect these spaces, management recommendations are complex due to variable conditions in urban natural areas. To advance the management of urban natural areas, the first comprehensive ecological assessment was conducted through a collaborative effort across 4000 ha of natural areas within New York City parkland. Field and spatial data were collected and analyzed to identify the extent of forests, the types of forests, and their conditions. This approach will help guide decision-making and prioritization of natural area management at the regional level by developing unique quantitative targets for urban forests. This project serves as an example of collaboration between private and public institutions advancing the governance of urban natural areas to achieve citywide conservation and policy goals.     

Ecosystem mapping for the implementation of the European Biodiversity Strategy at the national level: The case of Italy

Several international initiatives, including the European Biodiversity Strategy to 2020, promote the identification and mapping of ecosystems as basic tools for the conservation of biodiversity and related services. On coarse scales, the spatial representation of ecosystems is usually based on broad land cover categories that largely overlook important ecological and biogeographic features of the biotic communities they are meant to exemplify. This paper presents a nationwide ecosystem mapping approach that promotes a degree of thematic detail, which is more suited than that found in the continental maps to meeting biodiversity conservation targets in Italy. The approach is based on the rationale that current and potential vegetation cover are valuable proxies for outlining ecosystems. The resulting Ecosystem Map of Italy includes 43 types of forest ecosystems instead of the 5 woodland, forest and other wooded land types recognized at the European level. We outline the expected advantages of this enhanced thematic detail for a number of conservation purposes and highlight how the resulting maps may help to meet biodiversity conservation targets at the national level. In particular, we refer to the assessment of conservation status, the definition of restoration priorities, the planning of green infrastructure and the identification of collapse risks for the ecosystems identified. Comprehensively, the definition, characterization and assessment of ecosystem types represent the carrying structure of the recently launched national system of natural capital accounting.     

Bioaccumulation and biological effects in the earthworm Eisenia fetida exposed to natural and depleted uranium

The accumulations of both natural (U) and depleted (DU) uranium in the earthworms (Eisenia fetida) were studied to evaluate corresponding biological effects. Concentrations of metals in the experimental soil ranged from 1.86 to 600 mg kg⁻¹. Five biological endpoints: mortality, animals’ weight increasing, lysosomal membrane stability by measuring the neutral red retention time (the NRRT), histological changes and genetic effects (Comet assay) were used to evaluate biological effects in the earthworms after 7 and 28 days of exposure. No effects have been observed in terms of mortality or weight reduction. Cytotoxic and genetic effects were identified at quite low U concentrations. For some of these endpoints, in particular for genetic effects, the dose (U concentration)-effect relationships have been found to be non-linear. The results have also shown a statistically significant higher level of impact on the earthworms exposed to natural U compared to depleted U.     

Effects of three pesticides on the avoidance behavior of earthworms in laboratory tests performed under temperate and tropical conditions

Little research has been performed on the impact of pesticides on earthworms under tropical conditions. Taking into consideration the often-limited resources in tropical countries, simple screening tests are needed. Therefore, it was investigated whether three pesticides relevant for the Brazilian Amazon (benomyl, carbendazim, lambda-cyhalothrin) affect the avoidance behavior of the earthworm Eisenia fetida. The tests were performed for two days according to ISO guideline 17512 but were adapted to tropical conditions (i.e. test substrate, test organism and temperature). The results indicate that this test gives reproducible and reliable results. Toxicity values (NOEC, EC50) are lower than those determined in 14 day-acute mortality tests and are approximately in the same range such as those found in 56 day-chronic reproduction tests with the same earthworm species, which were performed in parallel. Therefore, the use of the earthworm avoidance tests is recommended as a screening tool for the risk assessment of pesticides.